Massless Majorana-Like Charged Carriers in Two-Dimensional Semimetals

The band structure of strongly correlated two-dimensional (2D) semimetal systems is found to be significantly affected by the spin-orbit coupling (SOC), resulting in SOC-induced Fermi surfaces. Dirac, Weyl and Majorana representations are used for the description of different semimetals, though the band structures of all these systems are very similar. We develop a theoretical approach to the band theory of two-dimensional semimetals within the Dirac–Hartree–Fock self-consistent field approximation. It reveals partially breaking symmetry of the Dirac cone affected by quasi-relativistic exchange interactions for 2D crystals with hexagonal symmetry. Fermi velocity becomes an operator within this approach, and elementary excitations have been calculated in the tight-binding approximation when taking into account the exchange interaction of π(pz)-electron with its three nearest π(pz)-electrons. These excitations are described by the massless Majorana equation instead of the Dirac one. The squared equation for this field is of the Klein–Gordon–Fock type. Such a feature of the band structure of 2D semimetals as the appearance of four pairs of nodes is shown to be described naturally within the developed formalism. Numerical simulation of band structure has been performed for the proposed 2D-model of graphene and a monolayer of Pb atoms.